Rhodium-carbonyl complexes with a quinolyl functionalized Cp-ligand: synthesis and photochemical activation

Dicarbonylη⁵-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(I) (1) was prepared by the reaction of Rh(CO)₂Cl]₂ with 2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl-potassium. Irradiation of 1 in chloroform or dichloromethane as solvent leads to the formation of dichloroη⁵-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium(III) (2). When Rh₆(CO)₁₆ is present, the cluster adds to the 8-quinolyl-cp-rhodium fragment and the compound η⁵-2,3,4,5-tetramethyl-1-(8-quinolyl)cyclopentadienyl]rhodium-di-μ-carbonyl-hexarhodiumtetradecacarbonyl (3) is formed in 65% yield. The coordination sphere of the rhodium(III) atom in compound 2 and of the rhodium(I) atom in 3 is completed by a coordination of the quinolyl moiety. This was revealed by NMR spectroscopy as well as by X-ray analyses.