A sigma 4, lambda 5-phosphinine palladium complex: a new type of phosphorus ligand and catalyst. Application to the Pd-catalyzed formation of arylboronic esters |
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| Authors: | Doux Marjolaine Mézailles Nicolas Melaimi Mohand Ricard Louis Le Floch Pascal |
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| Institution: | Laboratoire Hétéroéléments et Coordination, UMR CNRS 7653, Ecole Polytechnique, 91128 Palaiseau, France. |
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| Abstract: | A palladium(II) complex of a S-P-S pincer ligand featuring a metallated ylidic P-atom efficiently catalyzes the coupling between pinacolborane and various iodoaryls to yield the corresponding arylboronic esters (TON between 5100 and 76,500). |
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