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Directionality and borderline distance of secondary bonding on the fifth coordinate site in aluminium alkoxides
Authors:Lewiński Janusz  Zachara Janusz  Justyniak Iwona
Institution:Department of Chemistry, Warsaw University of Technology, 00-664 Warsaw, Poland. lewin@ch.pw.edu.pl
Abstract:A survey of the Cambridge Structural Database for alkylaluminium alkoxides has been used to determine the borderline distances and angular distributions of secondary interactions on the fifth coordinate site, and map out the minimum-energy pathways in associative reactions.
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