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Synthesis and Characterization of a New Titanium-silicate Material Containing Cage-like Polyhedral Oligosilsesquioxane
Authors:DING Han-ming  ZHANG Da-wei  LI Jiang  KONG Ai-guo  SHAN Yong-kui
Abstract:A new titanium-silicate material was synthesized with cubic cage-like tetramethylammonium octasilicate and TiCl4 ethanol solution as precursors. The product was characterized by FTIR, 29Si NMR, UV-Vis, and XRD. Structural and ingrediental analyses suggest that this material has a layered structure with cubic cage-like polyhedral oligosilsesquioxane as building blocks and titanium as bridging atoms.
Keywords:Polyhedral oligosilsesquioxane  Synthesis  Titanium-silicate material
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