Flow
microcalorimetry and thermokinetics of liquid mixtures |
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Authors: | M Rodríguez de Rivera F Socorro |
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Institution: | (1) Departamento Física, Universidad de Las Palmas, Las Palmas de Gran Canaria, Spain, 35017 |
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Abstract: | The identification of the calorimetric curves corresponding to liquid
mixtures for different injection flows, given by a flow microcalorimeter,
permits to classify in a kinetic way the studied mixtures. For this purpose,
it is determined the establishment time constant of the mixture (τmix)
that allows us to estimate the length occupied by the dissipation (through
the parameter λmix) and thus to justify the
sensitivity variation obtained in different chemical calibrations. |
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Keywords: | calibration flow microcalorimetry kinetic liquid mixtures sensitivity |
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