Solid contact ion sensor with conducting polymer layer copolymerized with the ion-selective membrane for determination of calcium in blood serum |
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Authors: | Natalia Abramova Javier Moral-Vico Jordi Soley Cristina Ocaña Andrey Bratov |
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Institution: | 1. BioMEMS Group, Instituto de Microelectrónica de Barcelona, Centro Nacional de Microelectrónica (CSIC), Campus U.A.B., 08193, Bellaterra, Barcelona, Spain;2. Lab. Artificial Sensors Syst., ITMO University, Kronverskiy pr. 49, 197101, St. Petersburg, Russia;3. Department of Chemical, Biological and Environmental Engineering, Escola d’Enginyeria, Universitat Autònoma de Barcelona, 08193, Bellaterra, Barcelona, Spain |
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Abstract: | A new solid contact ion selective electrode with intermediate conducting polymer (CP) layer formed by electropolymerization on a gold electrode of a bifunctional monomer, n-phenyl-ethylenediamine-methacrylamide (NPEDMA), which contains a methacrylamide group attached to aniline, is presented. The conducting polymer was studied by means of optical spectroscopy, cyclic voltammetry and potentiometric measurements. Ca2+-ion-selective membrane based on acrylated urethane polymer was shown to co-polymerize with the CP forming highly adhesive boundary that prevents formation of water layers between the CP and membrane, thus enhancing the stability and life-time of the sensor. The designed ion-selective electrode was successfully used for determination of total calcium ion concentration in blood serum samples. |
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Keywords: | Solid-contact ion selective electrode Conducting polymer Calcium ions Blood serum |
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