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Palladium-catalyzed asymmetric synthesis of axially chiral molecules |
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| Authors: | J C Fiaud and J Y Legros |
| Institution: | Laboratoire de Synthèse Asymétrique, Université Paris-Sud, Bât. 420, 91405 Orsay Cedex France |
| Abstract: | The asymmetric synthesis of chiral 3-alkylidene bicyclo3.3.0]octane and 4-substituted 1-alkylidene cyclohexane systems has been carried out (in up to 40% ee) by the palladium-catalyzed reaction of allylic acetates with sodium dimethyl malonate or morpholine. |
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