Synthesis of peroxide compounds by the BF3-catalyzed reaction of acetals and enol ethers with H2O2 |
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| Authors: | A O Terent"ev A V Kutkin M M Platonov I I Vorontsov M Yu Antipin Yu N Ogibin G I Nikishin |
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| Institution: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
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| Abstract: | Aliphatic and alicyclic gem-bis-hydroperoxides and their derivatives, bis(1-hydroperoxycycloalkyl) and bis(1-hydroperoxyalkyl) peroxides, dispiro- and tetraalkyl-1,2,4,5-tetroxanes were synthesized by the reaction of aliphatic and alicyclic acetals and enol ethers with H2O2 in the presence of BF3 in anhydrous Et2O. |
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| Keywords: | acetals enol ethers boron trifluoride complexes with Et2O and MeOH gem-bis-hydroperoxides bis(1-hydroperoxycycloalkyl) and bis(1-hydroperoxyalkyl) peroxides dispiro- and tetraalkyl-1 2 4 5-tetroxanes |
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