Abstract: | Using single crystal data the occurence of the K2NaCrF6 type of structure for Cs2NaInF6 (a = 8.905 Å) has been confirmed and xF determined to be xF = 0.229; in consequence: In–F = 2.039 Å 430 (hkl) with h + k = 2n and h = 0 to 7; R = 11.1%; Mo? Kα.]. The Madelung Part of Lattice Energy is calculated and discussed in detail. |