| A New Method for the Synthesis of C/D Ring Synthon of Vitamin D |
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| 引用本文： | Ling Jie GAO and Tian Zeng ZHAO,Guang Dian HAN(The institute of Chemistry,Henan Academy of Sciences,Zhengzhou,450003)Guang Dian HAN(Institute of Material Medica,Peking Union Medical College,Chinese Academy of Medical Sciences,Beijing,100050). A New Method for the Synthesis of C/D Ring Synthon of Vitamin D[J]. 中国化学快报, 1998, 0(3) |
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| 作者姓名： | Ling Jie GAO and Tian Zeng ZHAO Guang Dian HAN(The institute of Chemistry Henan Academy of Sciences Zhengzhou 450003)Guang Dian HAN(Institute of Material Medica Peking Union Medical College Chinese Academy of Medical Sciences Beijing 100050) |
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| 作者单位： | Ling Jie GAO and Tian Zeng ZHAO；Guang Dian HAN(The institute of Chemistry，Henan Academy of Sciences，Zhengzhou，450003)Guang Dian HAN(Institute of Material Medica，Peking Union Medical College，Chinese Academy of Medical Sciences，Beijing，100050) |
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| 摘 要： | Inrecentyears,vitaminDresearchareahasbeenstimulatedbythediscoveriesthatIQ,25-dihydroxyvitaminD,,theactivemetaboliteofvitaminD,,inadditiontotheclassicalrolesofregulatingcalciumandphosphorusmetabolisms',hasamuchbroaderspectrumofactivitiesthanoriginallythought,suchaspromotingcelldifferelltiationandinhibitingcellproliferation"'.Thebiologicalsignificanceandmedicalneedshaveledeffortstowardthesearchforanaloguesofpotentcelldifferelltiationandantiproliferationactivitywithouttoxichypercalcemiaassociate…
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A New Method for the Synthesis of C/D Ring Synthon of Vitamin D |
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| Ling Jie GAO and Tian Zeng ZHAO,Guang Dian HAN. A New Method for the Synthesis of C/D Ring Synthon of Vitamin D[J]. Chinese Chemical Letters, 1998, 0(3) |
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| Authors: | Ling Jie GAO Tian Zeng ZHAO Guang Dian HAN |
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| Abstract: | A C/D ring synthon of vitamin D is readily obtained from cholesteryl acetate viaoxidation, elimination of acetoxy group and Norrish type II photochemical reaction. |
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| Keywords: | C/D ring synthon vitamin D cholesteryl acetate photochemical degradation |
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