A calorimetrical study of the polynuclear Zn(II) and Pb(II) and the polymeric Ni(II) and Cd(II) complexes of 2-mercaptoethanol and 3-mercapto-1,2-propanediol期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

A calorimetrical study of the polynuclear Zn(II) and Pb(II) and the polymeric Ni(II) and Cd(II) complexes of 2-mercaptoethanol and 3-mercapto-1,2-propanediol

Authors:	H.F. De Brabander G.G. Herman L.C. Van Poucke

Affiliation:	Department of General and Inorganic Chemistry, University of Ghent, Ghent Belgium

Abstract:	The ΔG, ΔH and ΔS values for the dissociation of 2-mercaptoethanol (MEL) and 3-mercapto-1,2-propanediol and for the formation of complexes between these ligands and the metal ions Ni²⁺, Zn²⁺, Cd²⁺ and Pb²⁺ have been determined calorimetrically in 0.5 M KNO₃ and at 25°C.

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