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Profluorescent verdazyl radicals – synthesis and characterization
Authors:David Matuschek  Steffen Eusterwiemann  Linda Stegemann  Carsten Doerenkamp  Birgit Wibbeling  Constantin G Daniliuc  Nikos L Doltsinis  Cristian A Strassert  Hellmut Eckert  Armido Studer
Abstract:The synthesis and characterization of various 6-oxo-verdazyl radicals and their diamagnetic styryl radical trapping products are presented. It is shown that styryl radical trapping products derived from N-phenyl verdazyls show fluorescence whereas the N-methyl congeners are non-fluorescent. In the parent N-phenyl verdazyls fluorescence is fully quenched which renders these compounds highly valuable profluorescent radical probes.
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