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Magnetic MOF microreactors for recyclable size-selective biocatalysis
Authors:Jia Huo  Jordi Aguilera-Sigalat  Samir El-Hankari  Darren Bradshaw
Affiliation:a School of Chemistry , University of Southampton , Highfield Campus , Southampton SO17 1BJ , UK . Email: ; Tel: +44 (0)23 8059 9076
Abstract:In this contribution we report a synthetic strategy for the encapsulation of functional biomolecules within MOF-based microcapsules. We employ an agarose hydrogel droplet Pickering-stabilised by UiO-66 and magnetite nanoparticles as a template around which to deposit a hierarchically structured ZIF-8 shell. The resulting microcapsules are robust, highly microporous and readily attracted to a magnet, where the hydrogel core provides a facile means to encapsulate enzymes for recyclable size-selective biocatalysis.
Keywords:
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