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Self-organisation of dodeca-dendronized fullerene into supramolecular discs and helical columns containing a nanowire-like core
Authors:Sebastiano Guerra  Julien Iehl  Michel Holler  Mihai Peterca  Daniela A Wilson  Benjamin E Partridge  Shaodong Zhang  Robert Deschenaux  Jean-Fran?ois Nierengarten  Virgil Percec
Abstract:Twelve chiral and achiral self-assembling dendrons have been grafted onto a 60]fullerene hexa-adduct core by copper-catalyzed alkyne azide “click” cycloaddition. The structure adopted by these compounds was determined by the self-assembling peripheral dendrons. These twelve dendrons mediate the self-organisation of the dendronized 60]fullerene into a disc-shaped structure containing the 60]fullerene in the centre. The fullerene-containing discs self-organise into helical supramolecular columns with a fullerene nanowire-like core, forming a 2D columnar hexagonal periodic array. These unprecedented supramolecular structures and their assemblies are expected to provide new developments in chiral complex molecular systems and their application to organic electronics and solar cells.
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