| Synthesis and Structure of Inclusion Complex of Cyclomaltoheptaose（β—Cyclodextrin）with m—Aminophenol |
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| 引用本文： | 王瑾玲
,周卫红
,马世坤
,缪方明.Synthesis and Structure of Inclusion Complex of Cyclomaltoheptaose（β—Cyclodextrin）with m—Aminophenol[J].中国化学,2002,20(4):358-361. |
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| 作者姓名： | 王瑾玲 周卫红 马世坤 缪方明 |
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| 作者单位： | WANG，Jin-Ling ZHOU，Wei-Hong MA，Shi-Kun MIAO，Fang-Ming a Chemical and Life College，Tianjin Normal University，Tianjin 300074，China b Biological Department，Tsinghua University，Beijing 100871，China c Chemical Group，Tianjin Medical U |
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| 基金项目： | theFoundationofTianjinScientificCommittee (No .0 0 36 01711) |
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| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＳｕｐｒａｍｏｌｅｃｕｌｅｉｓａｋｉｎｄｏｆｓｙｓｔｅｍｗｉｔｈｓｐｅｃｉａｌｓｔｒｕｃ ｔｕｒｅｄｅｐｅｎｄｉｎｇｏｎｔｈｅｗｅａｋｍｏｌｅｃｕｌａｒｉｎｔｅｒａｃｔｉｏｎｓ (ｓｕｃｈａｓｖａｎｄｅｒＷａａｌｓ ,ｈｙｄｒｏｇｅｎｂｏｎｄ ,ｅｌｅｃｔｒｏｓｔａｔｉｃａｎｄｈｙ ｄｒｏｐｈｏｂｉｃｉｎｔｅｒａｃｔｉｏｎｓ) .Ｔｈｅｗｅａｋｉｎｔｅｒａｃｔｉｏｎｓａｒｅｒｅｌａｔｅｄｔｏｂｉｏｌｏｇｉｃａｌｐｒｏｃｅｓｓｅｓ ,ｆｏｒｅｘａｍｐｌｅ ,ｔｈｅｃａｔａｌｙｔｉｃｒｅａ…
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| 关 键 词： | 合成 晶体结构 包合配合物 β－环式糊精 m－氨基酸 |
Synthesis and Structure of Inclusion Complex of Cyclomaltoheptaose (β‐Cyclodextrin) with m‐ Aminophenol |
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| WANG,Jin-Ling ZHOU,Wei-Hong MA,Shi-Kun MIAO,Fang-Ming a Chemical and Life College,Tianjin Normal University,Tianjin ,China b Biological.Synthesis and Structure of Inclusion Complex of Cyclomaltoheptaose (β‐Cyclodextrin) with m‐ Aminophenol[J].Chinese Journal of Chemistry,2002,20(4):358-361. |
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| Authors: | WANG Jin-Ling ZHOU Wei-Hong MA Shi-Kun MIAO Fang-Ming a Chemical and Life College Tianjin Normal University Tianjin China b Biological |
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| Institution: | WANG,Jin-Ling ZHOU,Wei-Hong MA,Shi-Kun MIAO,Fang-Ming a Chemical and Life College,Tianjin Normal University,Tianjin 300074,China b Biological Department,Tsinghua University,Beijing 100871,China c Chemical Group,Tianjin Medical U |
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| Abstract: | The supramolecular compound, β‐CD/m‐aminophenol (C42H70O35)·(C6H7ON)·(H2O)7.5·CH3OH], was synthesized and characterized by X‐ray diffraction analysis. It crystallizes in monoclinic system, P21 space group, with a = 1.5122(4) nm, b=1.0335(4) nm, c=2.0915(3) nm, β=109.58(2)°, V = 3.0798(3) nm3 and final R = 0.0598. The system belongs to “shallow inclusion” which is rarely found. In this supramolecule, the guest is located over the narrow rim of the host There are so many hydrogen bonds that they build a dense hydrogen bond net. The hydrogen‐bond interactions are the main force to form the whole system and keep the stability. |
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| Keywords: | CD m-aminophenol synthesis crystal structure |
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