Structure of azo dye organotin(IV) compounds containing a C,N‐chelating ligand |
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| Authors: | Ale&#x; Ri
ka Antonín Ly
ka Roman Jambor Petr Novk Ivana ísa&#x;ov Michal Hol
apek Milan Erben Jaroslav Hole
ek |
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| Institution: | Aleš Růžička,Antonín Lyčka,Roman Jambor,Petr Novák,Ivana Čísařová,Michal Holčapek,Milan Erben,Jaroslav Holeček |
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| Abstract: | Two complexes derived from simple azo dyes (methyl orange and para‐methyl red) and the (2‐dimethylaminomethyl)phenyl](diphenyl)tin(IV) moiety have been prepared and their NMR, MS, IR, Raman and UV–VIS spectra were measured and X‐ray structures determined. Both compounds reveal the same structure in chloroform and in the solid state. The central tin atoms exist in a slightly distorted trans‐trigonal bipyramidal geometry. Copyright © 2003 John Wiley & Sons, Ltd. |
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| Keywords: | organotin(IV) compounds azo dyes C N‐ligand NMR X‐ray diffraction electrospray ionization mass spectrometry |
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