Crystallographic report: Bis[bis(N,N‐diethyldithiocarbamato)zinc(II)] (trans‐1,2‐bis(4‐pyridyl)ethylene)trans‐1, 2‐bis(4‐pyridyl)ethylene lattice adduct |
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| Authors: | Chian Sing Lai Edward R. T. Tiekink |
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| Abstract: | The dimeric and centrosymmetric structure of [Zn(S2CNEt2)2(trans‐NC5H4C(H)?C(H)C5H4N)]2 shows bidentate coordination by the dithiocarbamate ligands and a distorted square pyramidal geometry for zinc, defined by a NS4 donor set with the N atom in the apical position. The compound co‐crystallises with a centrosymmetric molecule of trans‐NC5H4C(H)?C(H)C5H4N that does not form a significant interaction to the Zn atom. Copyright © 2003 John Wiley & Sons, Ltd. |
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| Keywords: | crystal structure zinc dithiocarbamate diimine adduct lattice adduct |
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