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氮硫方酸与卤代烃的反应
引用本文:衡林森,彭大权.氮硫方酸与卤代烃的反应[J].四川大学学报(自然科学版),1995,32(6):686-689.
作者姓名:衡林森  彭大权
作者单位:达县师范专科学校,重庆师范专科学校,四川大学化学系
摘    要:氮硫方酸的巯基和氨基有较高的反应活性,利用巯基酸性较强易于成盐的特点,实现了氮硫方酸与卤代烃的选择性S-烃基化反应,成功地制得了11个相应的衍生物。

关 键 词:环丁烯二酮  氮硫方酸  S-烃基化反应  卤代烃

REACTION OF NITROGENSULFUR SQUARIC ACID WITH ALKYL HALIDES
Heng Linsen.REACTION OF NITROGENSULFUR SQUARIC ACID WITH ALKYL HALIDES[J].Journal of Sichuan University (Natural Science Edition),1995,32(6):686-689.
Authors:Heng Linsen
Abstract:Amino and mercapto group of nitrogensulfur squaric acid exhibited high reactivity. Since mercapto group had strong acidity and easy form salt,the reaction of selected s- aldylation fornitrogensulfur squaric acid with alkyl halides was brought about. Eleven compounds were succesfullyprepared.
Keywords:cyclobutenedione  nitrosulfur squaric acid  s-alkylation reaction  chemistry ofsquaric acid
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