Preconcentration of noble metals on a polymer support as complexes of organic reagents and their subsequent determination in the solid phase |
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Authors: | R F Gur’eva S B Savvin |
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Institution: | (1) Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, 117975 Moscow, Russia |
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Abstract: | Conditions of the sorption preconcentration of Pt, Pd, Au, Ag, and Hg as colored complexes of azorhodanines, tyrodine, and
sulfonitrophenol M from acidic solutions (pH 0–2) on a polyamide membrane in the flow mode are determined. At a flow rate
of 10–20 mL/min, concentrations of determined elements of 10-9-10-7 M, and pressure of 10–20 mm Hg, the complexes are nearly quantitatively sorbed on a polyamide membrane disk (d = 1 cm,m = 2.7 mg, andl = 0.1 mm). The influence of the composition of the test solutions on the formation of the analytical signal in the solid
phase is studied. Rapid sorption-spectrometric procedures are developed for the determination of Pt, Pd, Au, Ag, and Hg with
the detection limit 5–30 ng of the element in the sorbent zone |
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