Formation of carboxonium salts in the acylation of alkenes by acylium salts and some problems of the mechanism of acylation |
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| Authors: | O V Lyubinskaya V A Smit A S Shashkov V A Chertkov M I Kanishchev V F Kucherov |
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| Institution: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions Acylation of alkenes with branching at the allylic carbon provides a preparative route to cyclic carboxonium salts. Such salts can be prepared by protonation of ,  -unsaturated ketones —the products of acylation of unbranched alkenes. We have examined the mechanism of acylation of acylium salts.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 397–408, February, 1978. |
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