Improved Cope-type hydroamination reactivity of hydrazine derivatives |
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| Authors: | Loiseau Francis Clavette Christian Raymond Michaël Roveda Jean-Grégoire Burrell Alishya Beauchemin André M |
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| Institution: | Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, 10 Marie-Curie, Ottawa, ON K1N 6N5, Canada. |
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| Abstract: | A systematic investigation on the metal-free, Cope-type hydroamination reactivity of hydrazides and analogues is reported. Optimization of the hydrazide structure resulted in more facile intramolecular reactivity and enabled intermolecular reactions of alkenes, thus providing a direct approach to polysubstituted hydrazides. |
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