Anomalous magnetic susceptibilities of the alkaline earth hexammines |
| |
| Authors: | MJ Mobley WS Glaunsinger |
| |
| Institution: | Department of Chemistry, Arizona State University, Tempe, AZ 85281, U.S.A. |
| |
| Abstract: | The magnetic susceptibility of the metallic compounds Ca(NH3)6, Sr(NH3)6 and Ba(NH3)6 has been measured by the Faraday method in the range 2–200 K. The susceptibility of Ca(NH3)6 is strongly dependent on temperature and exhibits a broad minimum near 120 K and a peak near 10 K. In contrast to Ca(NH3)6, the susceptibilities of Sr(NH3)6 and Ba(NH3)6 are diamagnetic and decrease rapidly as the temperature is lowered. At low temperatures Ba(NH3)6 has the largest mass susceptibility of any nonsuperconducting metal. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
