A Samarium "Soluble" Anode: A New Source of SmI(2) Reagent for Electrosynthetic Application |
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| Authors: | Kamar Sahloul Linhao Sun Alexandre Requet Youhana Chahine Mohamed Mellah |
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| Institution: | Equipe de Catalyse Moléculaire, Univ Paris-Sud, ICMMO, UMR 8182, Orsay, 91405 (France), Fax: (+33)?169158046. |
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| Abstract: | An electrochemical method to prepare solutions of samarium diiodide in THF is reported. The simple electrolysis of a samarium rod provides a rapid and straightforward in situ synthesis of SmI(2) . The electrogenerated complex catalyzes various C?C bond formations. The reagent is produced continuously and leads to efficient organic electrosynthesis with significantly smaller amounts of solvent than usually required. |
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