Luminescence responsive charge transfer intercluster crystals |
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| Authors: | Ying Xiao Quan-Ming Wang |
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| Institution: | State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, Fujian, 361005 (P.?R. China), Fax: (+86)?592-2183047. |
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| Abstract: | POM and luminescence: The first charge transfer intercluster crystal has been synthesized by using Ag(62) S(13) (StBu)(32) ](4+) as the cation and Mo(6) O(19) (2-) as the anion. Its luminescence behavior is controlled by the electron accepting ability of the polyoxometalate (POM). The emission quenched by the charge transfer could be turned on by allowing the sample to contact halohydrocarbons. |
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