Reaction of singlet oxygen with α,β-unsaturated aldimines |
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Authors: | Takeshi Akasaka Kikuko Takeuchi Wataru Ando |
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Institution: | Takeshi Akasaka, Kikuko Takeuchi,Wataru Ando* |
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Abstract: | The reaction of singlet oxygen with N-1-(2-alkenylidene)-t- butylamines (
and
) gives the unsaturated hemiperacetal derivatives (
and 4) of the hydroperoxy aldimines (
and
). Several α, β-unsaturated aldimines which are held in the s-trans conformation failed to react with singlet oxygen. |
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Keywords: | |
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