The conductance of divalent Ions in H2O at 10 and 25°C and in D2O |
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| Authors: | T L Broadwater D F Evans |
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| Institution: | 1. Department of Chemistry, Howard University, Washington, D.C., 20001
2. Department of Chemistry, Case Western Reserve University, Cleveland, Ohio, 44106
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| Abstract: | Precise conductance measurements are reported for potassiumm-benzenedisulfonate and ferricyanide, for calcium, strontium, barium, and manganese chloride, and for manganese and potassium sulfate in D2O at 25°C. Measurements were also carried out in water at 10 and 25°C for all the salts with the exception of K3Fe(CN)6 at 10°C. Two runs are reported for sodium sulfate in water at 25°C. Limiting conductances of these ions are discussed in terms of solvent structural effects. The association constant for MnSO4 is found to be the same in H2O and D2O. |
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