Reaction of sulfolenes and their derivatives with some sulfur-containing nucleophiles |
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Authors: | T é Bezmenova T N Varshavets A Ya Bezmenov |
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Institution: | 1. Institute of the Chemistry of High-Molecular-Weight Compounds, Academy of Sciences of the Ukrainian SSR, Kiev
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Abstract: | Reaction of 2-sulfolene, 4-hydroxy-2-sulfolene, 4-bromo- and 3-chloro-2-sulfolenes, 3-chloro-4-hydroxysulfolane, and 3,4-dibromo(dichloro)sulfolanes with sodium methane-, hexane-, allene-, benzene-, and p-toluenesulfinates and magnesium gave 3-methyl-, 3-hexyl-, 3-allyl-, 3-phenyl-, and 3-(p-tolylsulfonyl)sulfolanes, 3-methyl-, 3-phenyl-, and 3-(p-tolylsulfonyl)-4-hydroxysulfolanes, and 3-phenyl- and 4-phenylsulfonyl-2-sulfolenes. |
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