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帽状锡纳米粒子的制备及其表面等离子的共振特性
引用本文:雷新宪,肖桂娜,满石清,杨兴旺.帽状锡纳米粒子的制备及其表面等离子的共振特性[J].物理化学学报,2009,25(1):169-172.
作者姓名:雷新宪  肖桂娜  满石清  杨兴旺
作者单位:Department of Physics, Jinan University, Guangzhou 510632;2.Institute of Nano-Chemistry, Jinan University, Guangzhou 510632
基金项目:国家自然科学基金,广东省自然科学基金,广东省自然科学基金团队项目,广州市科技计划项目 
摘    要:采用真空热蒸发法在SiO2自组装单层膜上沉积金属锡, 制备了帽状锡纳米结构, 通过扫描电镜(SEM)、原子力显微镜(AFM)、X射线衍射(XRD)仪和Cary 5000紫外-可见-近红外(UV-Vis-NIR)分光光度计对其表面形貌、结构以及光谱特性进行了研究和表征. 结果表明, 制备的复合纳米粒子呈帽状, 表面等离子共振峰位具有明显的可调谐性, 随二氧化硅粒径的增大或锡帽层厚度的增加, 表面等离子共振吸收峰向长波方向移动.

关 键 词:帽状锡纳米结构  复合纳米粒子  表面等离子共振  
收稿时间:2008-07-28
修稿时间:2008-09-26

Synthesis and Surface Plasmonic Resonance of Stannum Nanocaps
LEI Xin-Xian,XIAO Gui-Na,MAN Shi-Qing,YANG Xing-Wang.Synthesis and Surface Plasmonic Resonance of Stannum Nanocaps[J].Acta Physico-Chimica Sinica,2009,25(1):169-172.
Authors:LEI Xin-Xian  XIAO Gui-Na  MAN Shi-Qing  YANG Xing-Wang
Institution:Department of Physics, Jinan University, Guangzhou 510632;2.Institute of Nano-Chemistry, Jinan University, Guangzhou 510632
Abstract:Stannum nanocaps were prepared by evaporating Sn on self-assembled monolayer arrays of SiO2 nanoparticles. Surface morphologies, structure, and optical properties of composite nanoparticles were characterized and investigated using scanning electron microscopy (SEM), atomic force microscopy (AFM), X-ray diffraction (XRD) and UV-Vis-NIR spectrophotometer. The results show that the composite nanoparticles are cap-shaped and surface plasmonic resonance absorption peaks move to the near-infrared region as the SiO2 diameter increases and Sn cap thickness increases.
Keywords:Stannum nanocaps  Composite nanoparticles  Surface plasmonic resonance
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