Assembling of transitional metal CuII and MnII with 4-pyridin-2-yl-pyrimidine-2-sulfonate adjusted by anions |
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| Authors: | Huaze Dong Xia Liu Juan Yang Zhaolian Chu Wei Huang Shaohua Gou |
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| Affiliation: | (1) School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, China |
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| Abstract: | Reactions of sodium 4-pyridin-2-yl-pyrimidine-2-sulfonate (NaL) with CuII and MnII ions in water produced a zig-zag chain polymer, [CuL(NCS)] n (1), and a dinuclear complex, [Mn2L2Cl2(H2O)2] (2), respectively. It is observed that counteranions and hydrogen bonds play basic roles in the resulting structure in which 3D networks were formed through intermolecular hydrogen bonding. |
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