Bis(2,2′-bipyridine)(4,4′-diuntriacontanyl-2,2′-bipyridine)-ruthenium(II) chloride and related hydrophobic complexes |
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| Authors: | Kenneth R. Seddon Yousif Z. Yousif |
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| Affiliation: | (1) School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, Falmer, UK;(2) Department of Chemistry, College of Science, Basrah University, Basrah, Iraq |
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| Abstract: | Summary New synthetic routes to 1-triacontanol and 1-bromotriacontane, and the novel ligands 4,4 -diuntriacontanyl-2,2-bipy-ridine, 4-untriacontanyl-4'-methyl-2,2'-bipyridine and 4,4-ditricosyl-2,2-bipyridine are reported, as well as the preparation of the novel ruthenium(II) salts, [Ru(bipy)2(bipy-4-R-4-R)]Cl2 (bipy = 2,2'-bipyridine; R = R' = C31H63 or C23H47; R = C31H63, R' = Me). |
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