| 新颖的二维超分子化合物[CoⅢ(aea)(2,2′-bipy)]Cl·H2O的水热合成及结构表征(英) |
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| 引用本文： | 谢凤桐,段莉梅,徐吉庆,刘亚冰,张潇,卢静. 新颖的二维超分子化合物[CoⅢ(aea)(2,2′-bipy)]Cl·H2O的水热合成及结构表征(英)[J]. 无机化学学报, 2005, 21(1): 123-127 |
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| 作者姓名： | 谢凤桐 段莉梅 徐吉庆 刘亚冰 张潇 卢静 |
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| 作者单位： | 吉林大学无机合成与制备化学国家重点实验室，长春 130023;内蒙古通辽市产品质量计量检验所，通辽 028000,吉林大学无机合成与制备化学国家重点实验室，长春 130023,吉林大学无机合成与制备化学国家重点实验室，长春 130023,吉林大学无机合成与制备化学国家重点实验室，长春 130023,吉林大学无机合成与制备化学国家重点实验室，长春 130023,吉林大学无机合成与制备化学国家重点实验室，长春 130023 |
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| 摘 要： | A new compound [CoⅢ(aea)(2,2′-bipy)]Cl·H2O (aea=N-(2-aminoethyl)aspartate, 2,2′-bipy=2,2′-bipyridine) was hydrothermally synthesized and structurally characterized, which contains a new quadridentate ligand (aea) came from malic acid and ethylenediamine via in-situ reaction. The asymmetric molecules are interconnected through N-H…O hydrogen bond to form helical chains that are further hold together into a two-dimensional network via the N-H…Cl hydrogen bond. The formation of aea can be considered as the substitution of hydroxyl group in malate by ethylenediamino group, which presents a type of new in-situ ligand reaction. CCDC: 222018.
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| 关 键 词： | 超分子网络； 原位反应； Co(Ⅲ)配合物； 四齿配体 |
| 收稿时间： | 2004-06-30 |
| 修稿时间： | 2004-10-07 |
Hydrothermal Synthesisand Structural Characterization of a Novel 2-D Supramolecular Compound [Co |
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| XIE Feng-Tong,DUAN Li-Mei,XU Ji-Qing,LIU Ya-Bing,ZHANG Xiao and LU Jing. Hydrothermal Synthesisand Structural Characterization of a Novel 2-D Supramolecular Compound [Co[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(1): 123-127 |
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| Authors: | XIE Feng-Tong DUAN Li-Mei XU Ji-Qing LIU Ya-Bing ZHANG Xiao LU Jing |
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| Affiliation: | College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023;The Inspection Institute of Products Quality and Metrology of Tongliao City, Tongliao 028000,College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023,College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023,College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023,College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023 and College of Chemistry, State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023 |
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