Hydrolysis of alkenyl esters and ethers catalyzed by metal complexes |
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| Authors: | Aoyama Hiroshi Tokunaga Makoto Hiraiwa Shin-ichiro Shirogane Yuki Obora Yasushi Tsuji Yasushi |
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| Affiliation: | Catalysis Research Center and Division of Chemistry, Graduate School of Science, Hokkaido University and Japan Science and Technology Corporation (JST), Sapporo 001-0021, Japan. |
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| Abstract: | [reaction: see text] Various kinds of transition metals catalyzed the hydrolysis of alkenyl esters and ethers under buffer-free, high concentration conditions compared to usual biocatalysts. Hydrolytic kinetic resolution of cis-2-tert-butylcyclohexyl vinyl ether was achieved by chiral (salen)Co complexes with good selectivity (k(rel) = 10.0). |
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