Studying the uptake of aniline vapor by active alumina through in-line monitoring a differential adsorption bed with near-infrared diffuse reflectance spectroscopy |
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Authors: | Chen-Bo Cai Qing-Juan Han Li-Juan Tang Lu Xu Jian-Hui Jiang Hai-Long Wu Ru-Qin Yu |
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Institution: | (1) State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha, 410082, People’s Republic of China |
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Abstract: | Through non-invasive monitoring the uptake of aniline vapor by active alumina in a differential adsorption bed (DAB) with
near-infrared diffuse reflectance spectroscopy (NIR-DRS), we have studied several features of the adsorption, including isotherm,
kinetics and the chemical state of aniline molecules in aniline-alumina system. What is perhaps more important, since the
information above is obtained synchronously, the proposed methodology could provide information about the type of adsorption
(chemical or physical adsorption), the change of chemical state of aniline in the system during the adsorption process, whether
the chemical adsorption and physical adsorption took place simultaneously, the rate of the chemical and physical adsorption,
and so on. |
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Keywords: | Adsorption Differential adsorption bed Near-infrared spectroscopy In-line process analytical chemistry Partial least squares model Isotherm Kinetics Aniline Alumina |
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