Synthesis and Structure of a New Coordination Polymer Based on Indium and 1,4-Benzenedicarboxylate |
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| Authors: | LIN Zheng-Zhong CHEN Lian YUE Cheng-Yang JIANG Fei-Long HONG Mao-Chun |
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| Institution: | 1. College of Biological Engineering,Jimei University,Xiamen,Fujian 361021,China;State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sc
2. State Key Laboratory of Structural Chemistry,Fujian Institute of Research on the Structure of Matter,Chinese Academy of Sciences,Fuzhou,Fujian 350002,China |
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| Abstract: | A new coordination polymer {In(bdc)(OH)]'4H_2O}_n (H_2bdc=1,4-benzenedicarboxylic acid) has been synthesized through hydrothermal conditions,and was characterized by X-ray single-crystal diffraction and other measurements.The complex crystallizes in the orthorhombic system,space group Imma with a=18.3621(13),b=7.1932(5),c=11.8278(8) A,V=1562.24(19) (A)~3,Z=4.D_c=1.565 g/cm~3,M_r=368.00,F(000)=728,μ(MoKa)=1.542 mm~(-1),S=1.019,R=0.0468 and wR=0.1326 for 884 observed reflections (I ＞ 2σ(/)).The title compound represents a 3-D framework containing four kinds of tunnels in different shapes and sizes. |
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| Keywords: | indium 1 4-benzenedicarboxylate (bde) crystal structure coordination polymer |
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