| 高效液相色谱-三级四级杆质谱测定食品接触材料中6种全氟羧酸类化合物 |
| |
| 引用本文： | 蒋沁婷,刘慧婷,陈笑梅,郑自强,朱晓雨,谢文,王华雄.高效液相色谱-三级四级杆质谱测定食品接触材料中6种全氟羧酸类化合物[J].分析试验室,2010,29(3). |
| |
| 作者姓名： | 蒋沁婷 刘慧婷 陈笑梅 郑自强 朱晓雨 谢文 王华雄 |
| |
| 作者单位： | 1. 浙江出入境检疫检疫局,杭州,310012
2. 浙江大学生物系统工程与食品科学学院,杭州,310029 |
| |
| 基金项目： | 国家质检总局质检公益性行业科研专项(10-64)项目资助 |
| |
| 摘 要： | 采用高效液相色谱-串联质谱仪建立了食品接触材料中6种全氟羧酸类化合物(PFCAs)残留量的检测方法。通过对超声、振荡和离子配对3种方法的比较,选择超声法作为提取食品接触材料中PFCAs的提取方法,提取时间为30 min,提取溶剂体积为10 mL。提取物经C18色谱柱分离后由串联质谱检测。最低检测限为0.5μg/kg,添加回收率在84.6%～114.6%之间。
|
| 关 键 词： | 全氟羧酸类化合物 液相色谱串联质谱法 食品接触材料 |
Determination of perfluoroalkyl carboxylate compounds in food contact materials with HPLC-MS/MS |
| |
| JIANG Qin-ting,LIU Hui-ting,CHEN Xiao-mei,ZHENG Zi-qiang,ZHU Xiao-yu,XIE Wen,WANG Hua-xiong.Determination of perfluoroalkyl carboxylate compounds in food contact materials with HPLC-MS/MS[J].Chinese Journal of Analysis Laboratory,2010,29(3). |
| |
| Authors: | JIANG Qin-ting LIU Hui-ting CHEN Xiao-mei ZHENG Zi-qiang ZHU Xiao-yu XIE Wen WANG Hua-xiong |
| |
| Institution: | 1.Zhejiang Entry-Exit Inspection and Quarantine Bureau;Hangzhou 310012;2.College of Biosystem Engineering and Food Science;Zhejiang University;Hangzhou 310029 |
| |
| Abstract: | An trace analysis method was established to determine six kinds of perfluoroalkyl carboxylate compounds in food contact materials by high-performance liquid chromatography-tandem mass spectrometry(HPLC-MS/MS).Sonication was chosen to extract PFCAs from food contact materials after comparing ultrasonic extraction, shaking extraction and ion-pairing extraction.The extraction time and solvet volume was 30 min and 10 mL,respectively.The target compounds were separated on a C18 column and then detected by mass s... |
| |
| Keywords: | Perfluoroalkyl carboxylate compounds (PFCAs) High-performance liquid chromatography-tandem mass spectrometry (HPLC-MS/MS) Food contact materials |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
