Asymmetric hydrogenation of imines and olefins using phosphine-oxazoline iridium complexes as catalysts |
| |
| Authors: | Trifonova Anna Diesen Jarle S Andersson Pher G |
| |
| Affiliation: | Department of Chemistry, Organic Chemistry, Uppsala University, Box 599, SE-75124, Uppsala, Sweden. |
| |
| Abstract: | Herein we describe the synthesis of a new class of chiral phosphine-oxazolines and their application as ligands in iridium-catalyzed hydrogenations. Mechanistic aspects of olefin hydrogenation with this class of iridium catalysts are discussed and a selectivity model to help rationalize the results obtained is also presented. |
| |
| Keywords: | catalysis hydrogenation imine iridium olefin |
| 本文献已被 PubMed 等数据库收录！ |
|
