Synthesis and investigation of chemically modified silicas with the island structure of the grafted layer |
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Authors: | A Yu Fadeev R Yu Novotortsev G V Lisichkin |
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Institution: | (1) Chemistry Department, Moscow State University, Moscow, Russia |
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Abstract: | Island structures on the chemically modified surface of silica are synthesized by the method of matrix prints. Dichlorosilicon
phthalocyanine and copper naphthalocyanine were used as molecular templates. Two types of heterogeneous surfaces are prepared
by this method: the islands of nonmodified silica on the trimethylsilylated silica (the first type) and the islands of aminopropyl
silica on the esteric groups grafted on silica (the second type). The structure of the surfaces prepared is studied by ESR
spectroscopy with the use of paramagnetic probes. |
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