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Dipolar Order in Molecular Fluids: I. Toward an Understanding
Authors:Gunnar Karlström  Per Linse
Affiliation:(1) Microwave Research Lab, Department of Physics, Dr. B.A.M. University, Aurangabad, 431 004, India;(2) Microwave Research Lab, Department of Physics, Deogiri College, Aurangabad, 431 005, India;(3) Department of Computer Science and Electronics, Dr. B.A.M. University, Aurangabad, 431 004, India
Abstract:The origin behind the dipolar order in molecular fluids is investigated by using a simple dipolar fluid and Monte Carlo simulation technique. A penalty function is employed to separately manipulate the positional and orientational structure of the fluid. By considering the distance-dependent Kirkwood function G k, which in turn is related to the dielectric permittivity of the fluid, it is observed that both positional and orientational ordering are involved to establish dipolar order.
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