Synthesis,structure and reductive dechlorination of the C-centred phosphorus(III) beta-diketiminate PCl(Ph)L [L = C[C(Me)NC6H3Pri2(-2),6][C(Me)NHC6H3Pri2(-2),6] |
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| Authors: | Hitchcock Peter B Lappert Michael F Nycz Jacek E |
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| Affiliation: | Chemistry Laboratory, University of Sussex, Brighton, UK BN1 90J. |
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| Abstract: | Treatment of the beta-diketimine HL with successively LiBun and PCl2Ph gave the first C-centered monodentate beta-diketiminate PCl(Ph)L 1; with C8K 1 underwent reductive dechlorination yielding 2, a novel N-PIII-PIII-C=C heterocycle. |
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