Hydrogen bond and proton transfer in complexes of trioctylamine with halogenoacetic acids |
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| Authors: | G.S. Denisov G.V. Gusakova A.L. Smolyansky |
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| Affiliation: | Institute of Physics, Leningrad State University and Institute of Milk, Vologda U.S.S.R. |
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| Abstract: | The infrared spectra of solutions containing trioctylamine and monohalogenoacetic acids have been investigated in the region 1500–1800 cm?1. Two forms of complexes 1: 1 acid-amine, the molecular complex with hydrogen bond OH N and the ionic pair, resulting from proton transfer from acid to amine, have been found to exist in equilibrium with each other. |
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