Solution and single crystal raman spectra of potassium hexacyanochromate(III) |
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Authors: | P. Waage Jensen |
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Affiliation: | Department of Chemistry, Odense University, 5000 OdenseDenmark |
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Abstract: | Some inconsistency has existed in the assignment of the vibrational spectra of the Cr(CN)63? ion, and the crystal structure of K3Cr(CN)6 has been described both as monoclinic C2h5 and as orthorhombic D2h14. The solution and single crystal Raman spectra were recorded at room temperature. On the basis of these data a new assignment was made and the crystal structure was determined to be orthorhombic. |
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