Band intensities in the infrared spectra of metal carbonyl complexes: Chromium,molybdenum and tungsten hexacarbonyls |
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Authors: | SKh Samvelyan VT Aleksanyan BV Lokshin |
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Institution: | Institute of Organo-Element Compounds, Academy of Sciences, Moscow, USSR |
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Abstract: | The absolute integrated intensities for IR absorption bands of M(CO)6 (M = Cr, Mo, W) were measured. The calculations of dipole moment derivatives of the molecules were performed using a procedure suggested by L. S. Mayants and B. S. Averbukh. The effective atomic charges of M(CO)6 are estimated and discussed. |
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