Substituent effects on the proton spin-spin coupling of benzenes with side-chain interacting groups |
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| Authors: | D.G. De Kowalewski R. Buitrago R. Yommi |
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| Affiliation: | Departamento de Fisica, Facultad de Cienclas Exactas y Naturales, Ciudad Universitaria and Consejo Nacional de Investigaciones, Buenos AiresArgentina;Departamento de Fisica Universidad del Litoral, Santa FeArgentina |
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| Abstract: | Sixty MHz NMR proton spectra of 15 2,4-substituted benzaldehydes and 12 methylbenzenes dissolved in different solvents have been accurately analyzed. Substituent effects on the coupling constants have been determined and have been found to be additive in those trisubstituted compounds where there are neither internal hydrogen bonds or strong interacting groups present. |
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