Investigation of microphase separation in (K2OP2O5)x − (WO3)1−x glasses by electron microscope studies of surface replicas |
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Authors: | CW Bates Y Verhelle |
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Institution: | Department of Electrical Engineering and Materials Science and Engineering, Stanford University, Stanford, California 94305, USA;Department of Materials Science and Engineering, Stanford University, Stanford, California 94305, USA |
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Abstract: | Microphase sn the glass system (K2OP2O5)x ? (WO3)1?x for x = 0.48 and 0.33 was investigated. In both systems evidence of phase separation on a scale of 100 Å to 200 Å was found. The samples stayed completely amorphous during the cooling process but the two separate phases present in the glasses could unfortunately not be identified. These results coupled with conductivity versus mole percent of WO3 measurements suggest that the mechanism of phase separation is of the spinodal type. |
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