The rotational analysis of the gamma system (<span class="math"><math><mtext>A </mtext><msup><mi></mi><mn>3</mn></msup><mtext>Φ</mtext><mtext> - X′ </mtext><msup><mi></mi><mn>3</mn></msup><mtext>Δ</mtext></math></span>) of the spectrum of zirconium oxide期刊界 All Journals 搜尽天下杂志传播学术成果专业期刊搜索期刊信息化学术搜索

The rotational analysis of the gamma system ( $A^{3} Φ - X′^{3} Δ$ ) of the spectrum of zirconium oxide

Authors:	Jeremy B. Tatum Walter J. Balfour

Affiliation:	Department of Physics, University of Victoria, Victoria, British Columbia, Canada;Department of Chemistry, University of Victoria, Victoria, British Columbia, Canada

Abstract:	Rotational analyses of the (0,0), (1,1) and (2,2) bands, and a partial analysis of the (3,3) band, of the γ-system (A³Φ - X′³Δ) of the molecules ⁹⁰Zr¹⁶O, ⁹⁴Zr¹⁶O, ⁹⁶Zr¹⁶O have been performed. The measured wave numbers and their assignments are presented up to high quantum numbers. The rotational constants are calculated and an estimate is made of the spin-coupling coefficients. Both states belong closely to Hund's coupling case a.

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