Vibrational spectra of compounds Ln2MoO6 and Ln2WO6 |
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| Authors: | J.H.G. Bode H.R. Kuijt M.A.J.Th Lahey G. Blasse |
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| Affiliation: | Solid State Chemistry Department, Physical Laboratory, Sorbonnelaan 4, Utrecht, Netherlands |
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| Abstract: | The vibrational spectra of compounds Ln2WO6 and Ln2MoO6 (Ln = lanthanide, including Y and Bi) are reported. Neglecting details it is possible to assign the internal vibrations of the molybdate and tungstate group. The results are in agreement with the structural data known up till now and suggest further that tungsten in the unknown Y2WO6 structure is in six-coordination, that Bi2MoO6 shows still another modification than koechlinite and that vibrational spectroscopy may yield additional structural information for compounds like those under consideration. |
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