Fluorescent aromatic polyamides with urea binding sites and fluorene or dansyl signaling units |
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Authors: | Noelia San-José |
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Institution: | Departamento de Química, Facultad de Ciencias, Universidad de Burgos, Plaza de Misael Banuelos s/n, 09001 Burgos, Spain |
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Abstract: | This work describes six novel fluorescent aromatic polyamides with bulky dansyl or fluorene pendant groups or with the fluorene moiety in the main chain. The fluorescent signaling dansyl or fluorene moieties are chemically connected to, or within, the main polymer chains through a urea group, a well-known binding site in supramolecular chemistry. These polyamides are amorphous and soluble in polar aprotic solvents and demonstrate a film-forming capability. They also show yellowish-green or blue fluorescence in solution and in the solid state depending on the signaling unit, with the former corresponding to the dansyl and the latter to the fluorene residue. The water uptake and the thermal behavior have also been evaluated and related to the chemical structure. The polar amide, urea, and sulfonamide groups give rise to a high water sorption of up to 3.8 water molecules per repeating unit. The thermal behavior has been investigated by means of DSC and TGA. The glass transition temperatures of the polymers are high (up to 331 °C) and the decomposition temperatures (around 300 °C) are due to the moderate thermal stability of the urea group. |
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Keywords: | Polyamides Fluorescence Thermal properties Binding sites Signaling units |
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