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Study of charge storage in the nanofibrous poly(ethylene terephthalate) electrets prepared by electrospinning or by corona discharge method
Authors:Milena Ignatova  Asya Viraneva  Nevena Manolova
Institution:a Laboratory of Bioactive Polymers, Institute of Polymers, Bulgarian Academy of Sciences, Acad. G. Bonchev Street, Building 103 A, 1113 Sofia, Bulgaria
b Department of Experimental Physics, University of Plovdiv, 24 Tzar Assen Street, 4000 Plovdiv, Bulgaria
Abstract:In this paper, the charge storage performance of electrospun poly(ethylene terephthalate) (PET) mats with high specific surface area was evaluated in comparison to that of PET film electrets. Corona discharge method was used to charge the electrospun PET mats and PET films. The surface potential decay measurements revealed that the corona charged РЕТ mats had higher initial values for the normalized surface potential compared to the РЕТ electret films. A tendency for stabilization of the electret charge to one and the same value for all charged samples (mats and films) after the 50th day was observed. The peaks at 90 °C in the thermally stimulated current (TSC) spectra of uncharged and charged in corona discharge electrospun PET mats were observed and attributed to a relaxation of the separated space charges, the dipole disorientation or injected charges within the bulk. It was found that the value of the storage charge in a corona charged electrospun PET mats was higher than that in PET mats prepared by electrospinning.
Keywords:Poly(ethylene terephthalate)  Electrospinning  Electrospun electrets  Corona discharge  TSC (thermally stimulated current)
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