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Alkoholyse von Tris(dimethylamino)-arsin |
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| Authors: | Friedhelm Kober Werner Jürgen Rühl |
| Abstract: | Alcoholysis of Tris (dimethylamino)arsine The reaction of tris(dimethylamino)arsine with alcoholes and thioles leads to the formation of esters of the general formula As(XR)3 (X = O and S). The reaction is a suitable preparative method for the synthesis of the esters As(XR)3 (X = O and S). By alcoholysis in steps results an equilibrium system containing the molecules AsX3, AsX2Y, AsXY2, and AsY3 (X = OR, Y = N(CH3)2). |
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