Pillar[5]arene-based polymeric architectures constructed by orthogonal supramolecular interactions |
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Authors: | Yangfan Guan Mengfei Ni Xiaoyu Hu Tangxin Xiao Shuhan Xiong Chen Lin Leyong Wang |
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Institution: | Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China. lywang@nju.edu.cn. |
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Abstract: | Ureidopyrimidinone functionalized pillar5]arene (UPyP5) was synthesized and employed to complex with a bisparaquat derivative (G) to form supramolecular polymers at relatively high concentration. The orthogonal binding interactions including quadruple hydrogen bonding and host-guest interaction should play vital roles in the construction of this linear assembly. |
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